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List of Chapters

Mathematical Modeling and Reaction-Diffusion Processes at Ultra Microelectrodes


Author(s): S Anitha; K V Tamil Selvi*; K V Udayanatchi; L Rajendran*

The inimitable belongings of ultramicroelectrodes can be used for shaping thermodynamic and kinetic constraints of electrode progressions. By means of ultramicroelectrode through diverse radii, preceding (CE) and supplement responses of the ECE and EC’ nature can be quantitatively investigated. In this chapter, mathematical models for a ultramicroelectrode for the steady and transient states are discussed. Ultramicroelectrode can be modeled with linear and non-linear convection differential equations of EC’, EC, and ECE reactions mechanism. The chapter focuses on the behavior of ultramicroelectrodes. We discuss the recent modeling developments (analytical solution) of the concerntration produced and current in a ultramicroelectrode from all the electrochemical reactions are reviewed.